Polarographic maxima: influence of the nature of the electroactive species
β Scribed by H.H. Bauer
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 473 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0013-4686
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π SIMILAR VOLUMES
Maxima of the first kind involve streaming that arises from inequalities of the surface tension at different parts of the mercury drop. These inequalities arise from differences in the local interfacial potential and the latter arise from a non-uniform current-distribution. It is pointed out that t
Polarographic maxima studies of Cu, Pb, Zn and Mn systems in sodium nitrate revealed that character and magnitude of maximum was associated with the nature of the electroactive cation through the relationship of its E,,, to point of zero charge (pzc).
The equations for the influence of non-equilibrated, linear adsorption of a reactant, an intermediate and a product of the reversible redox reaction at stationary, planar electrode, under potentiostatic regime, have been derived.