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Polarized Raman spectra of KIO4 and RbIO4 and high-pressure Raman studies on KIO4

โœ Scribed by T. A. Al Dhahir; H. L. Bhat; P. S. Narayanan; A. Jayaraman


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
378 KB
Volume
22
Category
Article
ISSN
0377-0486

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โœฆ Synopsis


Abstract

Polarized Raman spectra of single crystals of KIO~4~ and RbIO~4~ were obtained. The observed fundamental modes satisfy the selection rules valid for the scheelite structure. The pressure dependence of the Raman spectra of KIO~4~, which was investigated up to 12 Gpa, reveals a structural phase transition in the crystal near 6.5 GPa, where new peaks are observed. Above 9.8 GPa only the peaks belonging to the highโ€pressure phase exist.


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