Experiments monitoring temporal recurrences of the fluorescence polarization anisotropy in a supersonic jet have been used to monitor the inertial properties of n-alkane complexes of the polycyclic aromatic hydrocarbon 2,5\_diphenylfuran (PPF). Semiempirical predictions for (he structure of the octa
Polarized fluorescence measurements of jet-cooled 2,5-diphenylfuran and van der Waals complexes
β Scribed by Andrew J. Kaziska; Maria I. Shchuka; Michael R. Topp
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 633 KB
- Volume
- 181
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Laser-induced fluorescence excitation spectroscopy in a supersonic expansion is used to evidence intermolecular chiral discrimination at the microscopic level. Measurements have been performed in (R)-(+)-and (S)-(-)-et-methyl-2-naphthalenemethanol (a naphthalene compound made chiral by the asymmetri
Laser-induced fluorescence spectra of Ne-and Ar-aniline complexes were observed with a resolution of 0.04 cm-l . By a simulation analysis of the rotational strucfures, the distances between the rare-gas atom and the aromatic ring of aniline were found fo be 3.35 f 0.04 and 3.50 + 0.04 4 in the X 'Al
The S& fluorescence excitation spectra of xanthione (XT) and azulene (AZ) complexed with 1 or 2 molecules of the C, to Cl0 n-alkanes and the C, to C, perfluoro-n-alkanes have been measured. The 1: I complexes exhibit microscopic solvent shifts, A& which are larger for the alkanes than the correspond