Polarization studies with thorium oxide
β Scribed by W.E. Danforth
- Publisher
- Elsevier Science
- Year
- 1958
- Tongue
- English
- Weight
- 462 KB
- Volume
- 266
- Category
- Article
- ISSN
- 0016-0032
No coin nor oath required. For personal study only.
β¦ Synopsis
Studies of electrical polarization resulting from passage of current in single crystals of thorium oxide in the 600Β°-1300 Β° C. region have been extended to detailed measurements of the initial rate of rise of such polarization. An attempt is made to deduce therefrom the density and mobility of charge carriers. Existing theoretical papers on the subject are briefly discussed. Reasonable values of carrier density are obtained but mobility values appear to be too low and to vary with temperature in the wrong sense. Probe measurements show that, for values of time less than one minute, the development of polarization EMF is confined to regions near the electrodes; for long times the polarization becomes more uniformly distributed throughout the crystal. Studies with constant voltage applied to a crystal show that, above a critical value of voltage, an instability develops in which the current increases to large values.
π SIMILAR VOLUMES
Studies have been made of the electrical polarization resulting from the passage of current in single crystals of low-oxygen thorium oxide at elevated temperatures . The emf . across the crystal necessary to maintain a constant current rises by a factor of 100 and more during the establishment of th
was measured and found to correspond to a 2--\* 2--~ 0 distribution, thus giving the spins of the first two excited states of Pt TM.
## 233 collision process which, on first view, at least, is almost unrecognizably different from the process as it occurs in the laboratory. Both defects of the standard treatment are readily remedied by employing a time dependent treatment which makes use of normalized state functions. The initia
Two novel potentiometric polymeric membrane sensors for rapid and accurate determination of thorium are described. These are based on the use of trioctylphosphine oxide (TOPO) and thorium toluate (Th-TA) as ionophores dispersed in poly(vinyl chloride) matrix membranes plasticized with nitrophenyloct