<div>This book offers an overview of polariton BoseEinstein condensation and the emerging field of polaritonics, providing insights into the necessary theoretical basics, technological aspects and experimental studies in this fascinating field of science. Following a summary of theoretical consider
Polaritonic Chemistry: Manipulating Molecular Structure Through Strong Light–Matter Coupling
✍ Scribed by Javier Galego Pascual
- Publisher
- Springer International Publishing;Springer
- Year
- 2020
- Tongue
- English
- Leaves
- 179
- Series
- Springer Theses
- Edition
- 1st ed.
- Category
- Library
No coin nor oath required. For personal study only.
✦ Synopsis
Polaritonic chemistry is an emergent interdisciplinary field in which the strong interaction of organic molecules with confined electromagnetic field modes is exploited in order to manipulate the chemical structure and reactions of the system. In the regime of strong light-matter coupling the interaction with the electromagnetic vacuum obliges us to redefine the concept of a molecule and consider the hybrid system as a whole. This thesis builds on the foundations of chemistry and quantum electrodynamics in order to provide a theoretical framework to describe these organic light-matter hybrids. By fully embracing the structural complexity of molecules, this theory allows us to employ long-established quantum chemistry methods to understand polaritonic chemistry. This leads to predictions of substantial structural changes in organic molecules and the possibility of significantly influencing chemical reactions both in the excited and ground states of the system.
✦ Table of Contents
Front Matter ....Pages i-xxi
Introduction (Javier Galego Pascual)....Pages 1-27
Theoretical Background (Javier Galego Pascual)....Pages 29-66
Molecular Structure in Electronic Strong Coupling (Javier Galego Pascual)....Pages 67-86
Theory of Polaritonic Chemistry (Javier Galego Pascual)....Pages 87-98
Manipulating Photochemistry (Javier Galego Pascual)....Pages 99-120
Cavity Ground-State Chemistry (Javier Galego Pascual)....Pages 121-156
General Conclusions and Perspective (Javier Galego Pascual)....Pages 157-163
✦ Subjects
Physics; Optics, Lasers, Photonics, Optical Devices; Quantum Physics; Quantum Optics; Inorganic Chemistry; Organic Chemistry; Physical Chemistry
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