✦ LIBER ✦
Polarisation ratio velocity dependence: A novel polarisation-sensitive technique for atom-diatom rotational energy transfer cross sections
✍ Scribed by A.J. McCaffery; M.J. Proctor; E.A. Seddon; A. Ticktin
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 306 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
In this communication we describe the polarisation ratio velocity dependence technique, using poiarisation-sensitive Doppler scan methods. Results from this technique aIIow us to report empirical evidence that the laboratory-fiied rate constants for different polarisation components (K = 0,l and 2), describing rotational energy transfer between Liz and xenon or helium, are temperature dependent and each follow different functions of the Doppler-selected molecular velocity.