Polar stationary phases for capillary electrochromatography
β Scribed by Chuanhui Xie; Hongjing Fu; Jiwei Hu; Hanfa Zou
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 439 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0173-0835
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β¦ Synopsis
Abstract
This review article summarizes the variety of polar stationary phases that have been employed for capillary electrochromatographic separations. Compared with reversedβphase stationary phases, the polar alternatives provide a completely different retention selectivity towards polar and charged analytes. Different types of polar stationary phases are reviewed, including the possible retention mechanisms. Electrochromatographic separations of polar solutes, peptides, and basic pharmaceuticals on polar stationary phases are presented.
π SIMILAR VOLUMES
Monolithic capillary electrochromatography CEC columns containing polymerized quinidine carbamate units have been prepared and used for enantioselective separations of modified amino acids. Optimization of both monolithic structure and mobile phase variables such as the ionic strength, type, and com