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Polar solvent effects on the homolytic decomposition of a perester

โœ Scribed by James C. Martin; David L. Tuleen; W.G. Bentrude

Book ID
104212171
Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
211 KB
Volume
3
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

THE enhancement ates containing acceleration by (Received Polar solvent effects No.6 isolated and t!le trapping of intermediates by radical scavengers indicate that thz dzcomoositions, for which these substituent and solvent effects arz observed, do follow a free-radical pathway. 2 ' P.D. Bart1et.t and C. Ruchardt,

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Peresters XIII. Solvent effects in the decomposition of t-butylperoxy ฮฑ-phenylisobutyrate with special reference to the cage effect
โœ Frank E. Herkes; Juliette Friedman; Paul D. Bartlett ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 663 KB

t-Butylperoxy or-phenylisobutyrate (I) decomposes thermally by concerted formation of carbon dioxide, t-butoxy, and cumyl radicals. Radical pair return in the solvent cage therefore does not affect the observed rate of decomposition, but is readily determined by means of galvinoxyl and other scaveng