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Polar Intermetallic Compounds as Catalysts for Hydrogenation Reactions: Synthesis, Structures, Bonding, and Catalytic Properties of Ca1−xSrxNi4Sn2 (x=0.0, 0.5, 1.0) and Catalytic Properties of Ni3Sn and Ni3Sn2

✍ Scribed by Viktor Hlukhyy; Fabian Raif; Peter Claus; Thomas F. Fässler


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
633 KB
Volume
14
Category
Article
ISSN
0947-6539

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Synthesis and Structure of [Sn4Se11]6–,
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Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re