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Polar and solvent effects in the reduction of substituted cyclohexanones

✍ Scribed by M.G. Combe; H.B. Henbest


Publisher
Elsevier Science
Year
1961
Tongue
French
Weight
257 KB
Volume
2
Category
Article
ISSN
0040-4039

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Hydrolysisofbicyclo[2.2.2]octylp-nitrobenzenesulfonate (14a,X =p-N02C6H4S03), and nineteen 4-R-substituted derivatives 14b-14 t in 70% aqueous dioxane yield the corresponding bicyclo [2.2.2]octanols 14 (X = OH), exclusively. The 7-center fragmentation to 1,4-dimethylidene-cyclohexane (15) is not obs