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Polar and free-radical additions of fluorinated species to unsaturated carbon-nitrogen systems

✍ Scribed by Kirchmeier, Robert L.; Lasouris, U. I.; Shreeve, Jean'ne M.

Book ID
127067796
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
688 KB
Volume
14
Category
Article
ISSN
0020-1669

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New Results of Free Radical Additions to
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✍ Metzger, J. O. ;Linker, Ursula πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons βš– 435 KB

Unsaturated fatty acids such as oleic acid are 1,2-dialkyl substituted alkenes, which can be functionalized by free radical addition to the C,Cdouble bond. We have been able to add enolizable compounds, e. g. acetone, acetic acid and malonic acid to methyl oleate mediated by manga- nese(II1)acetate.