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Polagraphic evidence for the formation of a cobalt(I) complex with terpyridine

โœ Scribed by D.J. Macero; F.V. Lovecchio; S.J. Pace


Book ID
114041096
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
398 KB
Volume
3
Category
Article
ISSN
0020-1693

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Polarographic evidence of the formation
โœ S.K. Dhar; Wayne E. Kurcz ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science โš– 187 KB

In a recent paper Musumecl et al.' described the polarographic reduction of bis(2,2',2"-terpyridine)cobalt(lI) perchlorate in acetonitrile to its zerovalent form [Co(terp)2]. Formally zerovalent [Co(bipy)3] is also reported in the literature 2, as well as the uni-negative Co(CO)~7 ion 3. However, no