## Abstract The polydomain–monodomain (PM) transformation takes place when a polydomain of a smectic‐C main‐chain liquid‐crystalline elastomer (SmC MCLCE) is uniaxially stretched. We present results based on a combination of mechanical and X‐ray experiments which show how the domains initially rear
Poisson's Ratio of Monodomain Liquid Crystalline Elastomers
✍ Scribed by Wanting Ren; Philip J. McMullan; Anselm C. Griffin
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 252 KB
- Volume
- 209
- Category
- Article
- ISSN
- 1022-1352
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✦ Synopsis
Abstract
Monodomains of smectic C liquid crystalline elastomers were prepared by controlled stretching of a polydomain thin film. Specimens were prepared from this film for stress–strain study. A Poisson's ratio of zero was found at small strains for uniaxial stretching perpendicular to the director. For uniaxial strain parallel to the director, Poisson's ratios of approximately 0.4–0.5 were found (by extrapolation) for very small strains. A modulus anisotropy of 8 was found for stretching parallel versus perpendicular to the director.
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Novel type of mesogenic chain extenders used in this study are N,NЈ-bis(4hydroxyphenyl)-3,4,3Ј,4Ј-biphenyldicarboxyimide (BPDI) and N, NЈ-bis[4-(6-hydroxyhexyloxy) phenyl]-3,4,3Ј,4Ј-biphenyldicarboxyimide (BHDI). BHDI has a flexible spacer of 6-methylene units but BPDI does not. The liquid crystalli
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