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Point Defect Dynamics and Evolution of Chemical Reactions in Alanates by Anelastic Spectroscopy

✍ Scribed by Palumbo, Oriele; Cantelli, Rosario; Paolone, Annalisa; Jensen, Craig M.; Srinivasan, Sesha S.


Book ID
127209889
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
145 KB
Volume
109
Category
Article
ISSN
0022-3654

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The formation of a highly mobile species during the decomposition reactions in Ti-doped and undoped sodium alanates is observed for the first time by anelastic spectroscopy. This species gives rise to a thermally activated relaxation peak around 70 K at 1 kHz, with an activation energy of 0.126 eV a