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P,N-Heterodifunctional ligands by selective Staüdinger reaction of β-substituted vinylazides with (Z)-1,2-bis(diphenylphosphanyl)ethene and formation of cyclometalled complexes of palladium(II) of these ligands — crystal and molecular structure of a new chiral cyclometallaphosphoraniminophosphane of palladium(II)

✍ Scribed by Antonio Arques*; Pedro Molina*; David Auñón; Marı́a Jesús Vilaplana; M.Desamparados Velasco; Francisco Martı́nez; Delia Bautista; Fernando J Lahoz

Book ID: 108356308
Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 206 KB
Volume: 598
Category: Article
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(99)00731-7

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Preparation of P,N-Heterodifunctional Ferrocene-Coordinating Ligands by Selective Functionalization of Polyphosphanes by the Staudinger Reaction – Crystal and Molecular Structure of a New Cyclometallaphosphoraniminophosphane of Palladium(II)

✍ Pedro Molina; Antonio Arques; Alejandro García; M. Carmen Ramírez de Arellano 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 655 KB

Staudinger reactions of the β-ferrocenylvinyl azide 1 with (triphos) and tris [2-(diphenylphosphanyl)ethyl]phosphane (tetraphos). Reaction of these P,N-difunctional ferrocene several diphosphanes in a 1:1 molar ratio afford the monoiminophosphorane derivatives 2-4, whereas with a 2:1 ligands with di