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PMR shift to high field induced by tris(dipivalomethanato)europium

โœ Scribed by S.B. Tjan; F.R. Visser


Book ID
104247982
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
150 KB
Volume
12
Category
Article
ISSN
0040-4039

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Tris (dipivalomethanato) europium - indu
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I J Tris(dipivalomethanato)e~opium(llI) has beem used as an NMR shift reagent to obtain simpli6ed spectra of tropine, of coordination was secondary amine > secondary alcohol > tertiary amine h ketone. . . .~ systems containing two different heteroatoms. The observed order tra of bifuictionai tropane

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## Applications of pammagnetic induced shifts of metal complexes (1) in PMR spectm to structure determinations of organic molecules (2) have recently been highlighted by Hinckley's discovery of tris(dipivalomethanato)bis(pyrIdino)europiun(III) [ Eu(DPM)a\*Pyz 1 as a shift reagent (3); thereafter,