Proton magnetic resonance has revealed itself as a method of choice in the investigation of isomeric oximes, since the anisotropy of the hydroxyimino group determines large chemical shift differences between syn and anti protons (1). Positive results in assignment by PMR have also been obtained from
PMR shift to high field induced by tris(dipivalomethanato)europium
โ Scribed by S.B. Tjan; F.R. Visser
- Book ID
- 104247982
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 150 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Like Wahl and Peterson,' we have recently used the NMR shift reagent, tris(dipivalomethanato)europium III [Eu(dpm)JZp3 to simplify the spectra of 2-hydroxyadamantane and in addition we have also studied a variety of I-R-adamantanes(R = (CH2),CH, n= 1, 2, 3) and cyclopentanol. Wahl and Peterson have
I J Tris(dipivalomethanato)e~opium(llI) has beem used as an NMR shift reagent to obtain simpli6ed spectra of tropine, of coordination was secondary amine > secondary alcohol > tertiary amine h ketone. . . .~ systems containing two different heteroatoms. The observed order tra of bifuictionai tropane
## Applications of pammagnetic induced shifts of metal complexes (1) in PMR spectm to structure determinations of organic molecules (2) have recently been highlighted by Hinckley's discovery of tris(dipivalomethanato)bis(pyrIdino)europiun(III) [ Eu(DPM)a\*Pyz 1 as a shift reagent (3); thereafter,