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PMR determination of the geometrical configuration of polychlorinated alkenes and alkadienes

✍ Scribed by R. Kh. Freidlina; V. I. Dostovalova; E. Ts. Chukovskaya; T. T. Vasil'eva

Publisher
SP MAIK Nauka/Interperiodica
Year
1974
Tongue
English
Weight
424 KB
Volume
14
Category
Article
ISSN
0022-4766

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NMR determination of the absolute config
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✍ Hiroki Fukui; Yukiharu Fukushi; Satoshi Tahara πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 217 KB

By the use of a new axially chiral reagent, 2'-methoxy-l,l'-binaphthalene-2-carbohydroximoyl chloride (MBCC), chiral cyclic alkenes were stereoselectively derivatized into 4,5-dihydroisoxazoles. NOEs were observed between the protons of the reagent moiety and those of the alkene moiety in cycloadduc