PMDR studies of intramolecular spin-orbit perturbations on the triplet state properties of substituted benzenes

✍ Scribed by G. Kothandaraman; D.S. Tinti

• Publisher: Elsevier Science
• Year: 1973
• Tongue: English
• Weight: 566 KB
• Volume: 19
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(73)85061-4

✦ Synopsis

PMDR studies on a series of hdobenzenes have shown that the in-plane electron spin distribution is highly perturbable and that spin-orbit contributions to the rektive energies of the spin states become significant in the heavier halobenzene:. A distortion in the triplet state of the heavier dihalobenzenes is also indicated.