PLIF Thermometry Based on Measurements of Absolute Concentrations of the OH Radical
✍ Scribed by Heinze, Johannes (author);Meier, Ulrich (author);Behrendt, Thomas (author);Willert, Chris (author);Geigle, Klaus Peter (author);Lammel, Oliver (author);Lückerath, Rainer (author)
- Book ID
- 120166869
- Publisher
- Oldenbourg Wissenschaftsverlag
- Year
- 2011
- Tongue
- German
- Weight
- 530 KB
- Volume
- 225
- Category
- Article
- ISSN
- 0942-9352
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The fast reaction of 0 atoms with NO2 has been used in measurements of absolute concentrations of 0 atoms. Similarly, the reaction of H with NO2 can be used to generate OH radicals in known concentrations. Relative concentrations of both 0 atoms and OH radicals have frequently been measured by reson
Absolute rate constants have been measured for the reaction of the OH radical with diacetylene over the temperature range of 296-688K using a flash photolysis-resonance fluorescence technique. The best fit to the data is given by the following Arrhenius expression: k= 1.11 x 10 -II exp{410+3OO(cal/m