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Platinum-Catalyzed Hydrosilylation of 2,2-Divinyladamantane

✍ Scribed by Giraud, Luc; Jenny, Titus

Book ID
127085512
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
160 KB
Volume
17
Category
Article
ISSN
0276-7333

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PtI 2 (PPh 3 ) 2 -catalyzed hydrosilylation of 2,2-diphenyl-1-methylenecyclopropane with HSiEt 3 forms (2,2-diphenylcyclopropyl)methyl(triethyl)silane in 87% yield as a sole product. This highly selective addition of Si H bond converts 2,2-diaryl-1methylenecyclopropane into its silylated derivative