Platinum-catalysed enantioselective hydroformylation of styrene. Platinum-diphosphine-tin(II) fluoride catalytic system: a novel asymmetric hydroformylation catalyst

Rhodium(I), Palladium(II), and Platinum(

Rhodium(I), Palladium(II), and Platinum(II) Complexes Containing New Mixed Phosphane−Phosphite Ligands − Effect of the Catalytic System Stability on the Enantioselective Hydroformylation of Styrene

✍ Carmela G. Arena; Felice Faraone; Claudia Graiff; Antonio Tiripicchio 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 297 KB 👁 2 views

The new mixed phosphane-phosphite ligands 1 and 2, derived from 3,3Ј-di-tert-butyl-2,2Ј-dihydroxy-5,5Ј-dimethoxybiphenyl and (S)-binaphthol, respectively, reacted with [Rh(COD)(THF) 2 ]CF 3 SO 3 to give the compounds [Rh(COD)(1)]CF 3 SO 3 and [Rh(COD)(2)]CF 3 SO 3 in which the ligands 1 and (S)-2 ar