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Platinum- and Gold-Catalyzed Cycloisomerization Reactions of Hydroxylated Enynes

✍ Scribed by Mamane, Victor; Gress, Tobias; Krause, Helga; Fürstner, Alois


Book ID
127177556
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
72 KB
Volume
126
Category
Article
ISSN
0002-7863

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Gold-catalyzed cycloisomerization reacti
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Gold (I) complexes generated from a mixture of gold and silver salts were found to be highly reactive for the cycloisomerization reactions of boronated enynes. Both alkynyl pinacol boronates and alkenyl pinacol boronates were tolerated, affording products in moderate to high yields. Interestingly, t