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Plasmon excitation in polycyclic aromatic hydrocarbons studied by photoionization

✍ Scribed by Yun Ling; Chava Lifshitz


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
299 KB
Volume
257
Category
Article
ISSN
0009-2614

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✦ Synopsis


The photoionization efficiency curves of phenanthrene, anthracene, fluoranthene, pyrene and triphenylene have been measured by VUV photoionization. All spectra show a similar resonance peak at around 17 eV. This phenomenon can be explained as being due to autoionization via a giant plasmon resonance. Autoionization has a negligible contribution to fragmentation processes which occur in the same energy range.


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