✦ LIBER ✦

Planar to Linear Structural Transition in Small Boron−Carbon Mixed Clusters: C x B 5 −x − ( x = 1−5)

✍ Scribed by Wang, Lei-Ming; Averkiev, Boris B.; Ramilowski, Jordan A.; Huang, Wei; Wang, Lai-Sheng; Boldyrev, Alexander I.

Book ID: 121442489
Publisher: American Chemical Society
Year: 2010
Tongue: English
Weight: 653 KB
Volume: 132
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja103846q

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

New Double Salts with Boron-Centered Zir

New Double Salts with Boron-Centered Zirconium Clusters: Syntheses and Structures of Cs[ZrCl5]×Cs2[(Zr6B)X15] (X: Cl or Cl + I), and Anion Distribution in the Mixed Halide Phase.

✍ Henning W. Rohm; Martin Koeckerling 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 79 KB 👁 2 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Attaching Metal-Capped sp Carbon Chains

Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries More Distorted than Planar Tetracoordinate

✍ Stephen B. Falloon; Slawomir Szafert; Atta M. Arif; J. A. Gladysz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 280 KB 👁 2 views

Reaction of [(h 5 -C 5 Me 5 )Re-(NO)(PPh 3 )(CCH)] (1) and [Os 3 -(CO) 10 (NCCH 3 ) 2 ] (CH 2 Cl 2 , room temperature) gives the ReC 2 Os 3 complex [(h 5 -C 5 Me 5 )Re(NO)(PPh 3 )(CC)Os 3 -(CO) 10 (H)] (2, 78 %). The crystal structure shows that the hydride and ReCC terminus bridge the same two osmi

Reactions of monoazadienes with metal ca

Reactions of monoazadienes with metal carbonyl complexes. 1. Reaction of N-alkyl-(E)-crotonaldimine with ruthenium dodecacarbonyl. The molecular structure (x-ray) of the linear 66-electron tetraruthenium cluster Ru4(CO)10(MeC:CHCH:NCHMe2)2, which is isolobally related to [(.eta.5-C5H5)Ru(CO)(.mu.-CO)]2

✍ Polm, Louis H.; Mul, Wilhelmus P.; Elsevier, Cornelis J.; Vrieze, Kees.; Christo 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 931 KB

Structure expansion of the mixed-metal d

Structure expansion of the mixed-metal dicarbide cluster core in [(μ3-CC-Fp)Ru3(μ-H)(CO9)] via direct radical and thermal coupling reactions leading to higher-nuclearity (μ-C2Hx)My cluster compounds (x = 0, 1; y = 7, 8), CpFeRu6(μ5-C2)(μ5-C2H)(CO)16, Cp2Fe2Ru5(μ5-C2)2(CO)17 and Cp2Fe2Ru6(μ6-C2)2(CO) 17

✍ Munetaka Akita; Hideki Hirakawa; Masako Tanaka; Yoshihiko Moro-oka 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 275 KB

Ligand-induced polyhedral opening in the

Ligand-induced polyhedral opening in the mixed-metal cluster MeCCo2NiCp(CO)6by 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray structure of Co2NiCp(CO)4[μ2,η2,η1-C(Me)C=C(PPh2)C(O)CH2C(O)](μ2-PPh2)

✍ William H. Watson; Krzysztof Ejsmont; Jie Liu; Michael G. Richmond 📂 Article 📅 2006 🏛 Springer 🌐 English ⚖ 293 KB

Additions and Corrections - Synthesis of

Additions and Corrections - Synthesis of triangular mixed-metal clusters by the addition of copper electrophiles to an electron-rich rhodium-rhodium bond. X-ray crystal structures of [Rh2(.eta.-C5H5)2(.mu.-CO)(.mu.-Ph2PCH2PPh2)(.mu.-CuI)] and [Rh2(.eta.-C5H5)2(.mu.-CO)(.mu.-Ph2PCH2PPh2)(.mu.-AgO2CCF3)] [Erratum to document cited in CA107(23):217829Q]

✍ Bruno, Giuseppe.; Lo Schiavo, Sandra.; Rotondo, Enrico.; Piraino, Pasquale.; Far 📂 Article 📅 1988 🏛 American Chemical Society 🌐 English ⚖ 130 KB