Pinacol Reduction of 1,2-Dibenzoylethane. Formation of a Strained Cyclic Pinacol
β Scribed by Griffin, Gary W.; Hager, Robert B.
- Book ID
- 126881066
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 314 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Aliphatic 1,5-and 1,6 dialdehydes with and without a-substituents, as well as derivatives of carbohydrate dialdehydes undergo a pinacol coupling reaction in the presence of SmI;! to give cis-diols as the preponderant products. When cc-alkoxy groups are present, the diol has an orientation that is op
## Abstract For Abstract see ChemInform Abstract in Full Text.
OGPIneneglyaol monotoeylete II derived from I (1) wee treated with methenollc poteaslum hydroxide. The main product from II was found 1968) to be a member of the blcyclo[2.1.4 hexane series. This observation Is the first example of ring contraction of a member of the plnane group to this highly str
The inter-and intramolecular coupling of imines promoted by samarium diiodide and Lewis acids or by Zn/MsOH was extensively studied. The intramolecular reaction of chiral, enantiomerically pure bis-imines was also considered, and allowed the efficient, stereoselective synthesis of 1,2-diamines with