Pinacol rearrangemet of 3-endo-phenyl-2,3-exo,-cis-bornanediol. An endo-endo hydride migration
โ Scribed by Bushell, Alan W.; Wilder, Pelham.
- Book ID
- 127033657
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 261 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The allylboron reagent 4 prepared .from endo-2-phenyl-exo-2,3-bornanediol reacts with achiral aldehydes to give homoallylic alcohols in good yields and high enantioselectivity (70-85% ee). This new reagent also exhibits good levels of matched and mismatched diastereoselection in reaction with chiral
## Abstract A number of stereoisomeric Nโ[aryl(alkyl, cycloalkyl)carbonyl]โexo(endo)โ5โaminomethylbicyclo[2.2.1]heptโ2โenes have been synthesized from bicyclo[2.2.1]heptโ2โenโexo(endo)โ5โcarbonitrile via reduction of the latter by lithium aluminum hydride and subsequent reactions of the resulting a