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Pinacol closure of oxygenated taxane skeleta at C-1-C-2 with stereoinduction by oxygen substituents at C-9 and C-10

✍ Scribed by Charles S. Swindell; Weiming Fan; Peter G. Klimko

Book ID: 104214511
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 310 KB
Volume: 35
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)73292-8

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✦ Synopsis

The trameat of keto aldehydes 4 and 5 with low-valent Ti results in stexoselective intraamkcutaf pimcol coqaings that lead to optically ache oxyg&maed taxane skkta 2 and 3.

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