## Abstract The emission band of the isoelectronic impurity Te in CdS is investigated with static uniaxial stress, σ, applied to the crystal. It is suggested that the bandshape is due to strong electron‐LA‐phonon interaction, the corresponding coupling constant and the effective phonon energy are d
✦ LIBER ✦
Piezoemission Study of Free Excitons in CdS
✍ Scribed by O. Goede; A. Büchtemann
- Book ID
- 104543628
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 465 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0370-1972
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✦ Synopsis
Abstract
The free exciton emission bands in CdS are investigated with static uniaxial stress, σ, applied to the crystal. The measured peak shifts and intensity ratios as function of stress σ ∥ c and σ ⟂ c are interpreted on the basis of first order perturbation theory and lead to quantitative information on the stress‐induced mixing of exciton states. In particular, the A(Γ~6~)‐exciton, stress‐allowed for σ ⟂ c, is studied and the corresponding mixing matrix element is determined. For both stress directions a Boltzmann distribution of the exciton concentrations is found.
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