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Picosecond Transient Infrared Spectrum of 4-(Dimethylamino)benzonitrile in the Fingerprint Region

โœ Scribed by Okamoto, Hiromi

Book ID
127238244
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
93 KB
Volume
104
Category
Article
ISSN
1089-5639

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A picosecond infrared spectrometer covering nearly the whole fingerprint region has been constructed. The infrared absorption spectrum of electronically excited (S~ state) 4-dimethylamino-4'-nitrostilbene, which is considered to have an intramolecular charge-transfer character, has been recorded. Th

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The rate of formation of the intramolecular charge-transfer state of 4-(N,N-dimethylamino)benzonitrile (DMABN) has been determined in supercritical CFsH using a fast single-photon counting technique. The rate constant increases rapidly with increasing CFIH density, indicating the importance of the p