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Picosecond spectroscopic investigation of the internal conversion rate of excited perylene in solution

โœ Scribed by C. Rulliere; A. Declemy; Ph. Kottis

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
676 KB
Volume
110
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

l'he dynamics ot relaxation from upper vibrational levels of the ST state and from the upper vibronic states S: and .S: of per) Icnc dis';olvcd m orgmc solvents of vGz~us vlscositles and pohities have been invcstipnted. Uneqxcted slow dewy times hvc been me,wwd. of 11~ order of 30 ps for vibrational rchation in the ST rwnifold and of tlw order of 50-60 ps for mrcmal cooverwn from state% S; and S:. Signi!icant solvent effects hve not been observed on &an&~ the pal&y +tnd the \zscosity of the sohenr.

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