The solvation dynamics of a rigid polar probe dissolved in highly polar aprotic solvents has been studied using time-resolved fluorescence techniques. We have observed good correlation between the characteristic solvation time ra and the microscopic relaxation time rM of the individual solvent molec
Picosecond solvation dynamics: the role of the solvent microscopic relaxation time in highly polar aprotic solvents
✍ Scribed by A. Declémy; C. Rulliére
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 57 KB
- Volume
- 148
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
With the help of G. Scuseria and H.F. Schaefer III, we have found an improper factor of 2 in non-linear HN T: contributions to T, amplitudes only for the fill CCSDT results. This caused minor changes in table 3. As these small basis results may be used as reference calculations, we report the corrected results with the final digits changed from the reported values shown in parentheses. The small differences obviously do not affect any conclusions.
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