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Picosecond rotational diffusion by differential single-photon fluorescence spectroscopy

✍ Scribed by R.W.Wijnaendts van Resandt; L. de Maeyer


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
451 KB
Volume
78
Category
Article
ISSN
0009-2614

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✦ Synopsis


The rotatIonal dlffuuon contanrs of rhodanunedG, coumarin-1 and N-acetyltryprophanamxde in various solvents have been determuted by an experimental method where the vertxally and honzontally polarized fluorescenm spectra are masured stmultaneously by the same detector The rest&s indicate that the Debye-Stokes-Emsteu model does not hold for coumarin-i and N-acetyltryptophxnamtde 111 ethylene glycol


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✍ G. Porter; P.J. Sadkowski; C.J. Tredwell πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 498 KB

The rotational diffusion time constants of tetrachlorotetraiodotluorescein in a series of low viscosity, hydrogen bonding solvents have been determined by picosecond time-resolved fluorescence depolarisation spectroscopy. Steady state measurements of this dye and rhodamine 6G have been used to obtai