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Picosecond kinetic and vibrationally resolved spectroscopic studies of intramolecular excited-state hydrogen atom transfer

✍ Scribed by Barbara, Paul F.; Walsh, Patrick K.; Brus, Louis E.


Book ID
115518953
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
685 KB
Volume
93
Category
Article
ISSN
0022-3654

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Intramolecular 2pΟ€* β†’ 3dΟ€ charge transfe
✍ Haruo Shizuka; Katsuhiko Okazaki; Masayuki Tanaka; Mitsuo Ishikawa; Minoru Sumit πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 366 KB

In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra