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.pi.-Arene Complexes. 10. Arene Distortions in .pi.-Arene Complexes of Chromium by Ring Substituents. Crystal Structure of (.eta.1:.eta.6-C6H5{TiCp2Cl})Cr(CO)3

✍ Scribed by Meyer, Rita; Schindehutte, Minet; van Rooyen, Petrus H.; Lotz, Simon

Book ID: 127032054
Publisher: American Chemical Society
Year: 1994
Tongue: English
Weight: 460 KB
Volume: 33
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00094a027

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Organometallic complexes with electronic

Organometallic complexes with electronic bridges. 9. .pi.-Donor interactions and the origin of arene nonplanarity in heterobimetallic (.eta.6-arene)chromium tricarbonyl complexes having .sigma.-bonded organometallic substituents: X-ray crystal structures of (.eta.6-C6H5((.eta.5-C5H4Me)Fe(CO)2))Cr(CO)3, (.eta.6-C6H5((.eta.5-indenyl)Fe(CO)2))Cr(CO)3, and (.eta.6-1,4-C6H4Me((.eta.5-C5H5)Fe(CO)2))Cr(CO)3

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Preparation and x-ray crystal structure

Preparation and x-ray crystal structure analysis of the hydroxo-bridged, dinuclear (.pi.-arene)ruthenium(II) cation in [Ru2(.eta.6-C6H6)2(.mu.-OH)3]Cl.3H2O

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