Physicochemical properties of Schiff bases. 4. Tautomeric equilibrium and kinetics of hydrolysis of N-benzylideneaniline derivatives
โ Scribed by Charette, J. J.; De Hoffmann, E.
- Book ID
- 127227076
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 754 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-3263
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The rate of hydrolysis of title schiff bases was studied in the pH range 4-13 in 10% dioxanewater system, CTAB, NaLS micellar solutions. The hydrolysis was found to be due to 'water' and 'hydroxide' reactions and hence the rate constants in different pH were computed and analyzed with an intermediat
We have carried out a kinetic study of the 4-pyridinecarboxaldehyde plus n-hexy-Iamine system, at 25T, in water-dioxan mixtures (0-608 v/v) and in the pH range pK, + 1.5 > pH > pK, -1.5, where pK, is the pK value of the conjugate acid of the amine. The results obtained could be interpreted in terms