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Physicochemical properties of 1,2-epoxycyclopentane

✍ Scribed by A. E. Meshechkina; L. V. Mel’nik; G. V. Rybina; S. S. Srednev; Yu. A. Moskvichev; A. S. Danilova; Z. V. Kostyuk

Book ID
111462816
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
284 KB
Volume
82
Category
Article
ISSN
1070-4272

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Non-enolizable thioketones and 1,2-epoxycycloalkanes undergo a Lewis acid catalyzed addition reaction to give 1,3-oxathiolanes. Appropriate reaction conditions are CH 2 Cl 2 as the solvent, BF 3 ´Et 2 O as the Lewis acid, and a temperature between À 788 and r.t. Under the reaction conditions, the 1,