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Physical techniques in the study of silver catalysts for ethylene oxidation.


Publisher
Elsevier Science
Year
1960
Tongue
English
Weight
88 KB
Volume
10
Category
Article
ISSN
0042-207X

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Size effects in ethylene oxidation on si
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A new method for preparing supported silver catalysts with a narrow particle size distribution has been developed. For crystals with a diameter ranging from 100 to 1000 ,~ the dependencies of reaction rates on size have been studied for epoxidation and deep oxidation of ethylene. For particles 300-5

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X-ray photoelectron spectroscopy (XPS) has been applied to the study of a series of metaliocene catalysts, containing Zr, Ti or Hf. for the polymerization of ethylene. Surface atomic compositions, binding energies and valence band (VB) spectra have been measured. Surface compositions were found to b