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Physical properties of stable monoclinic and metastable trigonal 4-methylbenzophenone

✍ Scribed by Klapper, Helmut; Kutzke, H.; Haussühl, Siegfried


Book ID
120394886
Publisher
Oldenbourg Wissenschaftsverlag
Year
2000
Tongue
English
Weight
93 KB
Volume
215
Category
Article
ISSN
2194-4946

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✦ Synopsis


Pyroelectric, dielectric and piezoelectric coefficients of metastable 4-methylbenzophenone, point group 3, have been determined by standard methods. Furthermore, thermal expansion and elastic properties of this phase and of the stable monoclinic phase have been studied. The pyroelectric effect is comparable with that of tourmaline, the piezoelectric effects to those of a-quartz. The differences between the two polymorphs with respect to thermal expansion and to elastic and thermoelastic properties are small, but nevertheless significant.


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Polycrystalline samples and single crystals of the R 4 Mo 4 O 11 compounds (R ¼ Yb and Lu) were synthesized by solid-state reactions at high temperature in sealed Mo crucibles. The structure of Lu 4 Mo 4 O 11 (a ¼ 10.5611(1), b ¼ 5.61930(5), c ¼ 15.6877 (2), b ¼ 99.5131(4) and Z ¼ 4) was determined