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Physical properties of polyhedral oligomeric silsesquioxanes–cycloolefin copolymer nanocomposites

✍ Scribed by Andrea Dorigato; Alessandro Pegoretti; Claudio Migliaresi


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
526 KB
Volume
114
Category
Article
ISSN
0021-8995

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## Abstract All siloxane‐type siloxane–polyhedral oligomeric silsesquioxane [(HSiO~3/2~)~8~, T~8~^H^] copolymers were synthesized by the dehydrogenative condensation of T~8~^H^ with diphenylsilanediol, tetraphenyldisiloxane‐1,3‐diol or silanol‐terminated polydimethylsiloxanes in the presence of die

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## Abstract **Summary:** We have synthesized a new polyhedral oligomeric silsesquioxane (POSS) containing eight phenol functional groups and copolymerized it with phenol and formaldehyde to form novolac‐type phenolic/POSS nanocomposites exhibiting high thermal stabilities and low surface energies.