Radiation-induced graft polymerization of acrylic acid onto poly(tetrafluoroethylene-perfluorovinyl ether ) copolymer films has been prepared using g-irradiation by the mutual method. The grafted copolymer rapidly complexes with rhodium ions through the carboxylic groups. The complexation process wa
Physical properties of graft copolymer-metal complexes obtained by radiation grafting onto poly(tetrafluoroethylene-co-perfluorovinyl ether)
✍ Scribed by Naeem M. El-Sawy; M.A. Abd El-Ghaffar; El-Sayed A. Hegazy; Ahmed Dessouki
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 406 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
Grafting of aqueous acrylic acid onto poly(tetrafluoroethylene-co-perfluorovinyl ether) films has been carried out using 7-irradiation. Copper and chromium complexes have been prepared by treating the grafted films with aqueous solutions of copper and chromium sulphates. The formation of polymer/metal complexes has been confirmed spectrophotometrically by u.v. and colour measurements. Electrical and mechanical properties of films of the complexes have been studied. Thermal analysis and study of the effect of u.v. on the polymer metal complexes have been also undertaken.
📜 SIMILAR VOLUMES
## Abstract To introduce functional moieties to a poly(tetrafluoroethylene‐__co__‐perfluorovinyl ether) film, graft copolymerization of vinyl monomers such as acrylic acid was attempted by a simultaneous technique in aqueous solution using γ‐irradiation. The graft copolymers were complexed with the
Cationic membranes were prepared by direct radiation grafting of acrylic acid (AAc) and methacrylic acid (MAA) onto poly(tetrafluoroethy1eneperfluoropropylvinyl ether) (PFA) films, followed by alkaline treatment to confer ionic character in the graft copolymer. The addition of inhibitor such as Mohr