✦ LIBER ✦

Physical Organic Chemistry of Transition Metal Carbene Complexes. 26. † Kinetics and Mechanism of the Reactions of [Phenyl(thiomethyl)carbene]pentacarbonylchromium(0) with Amines in Aqueous Acetonitrile

✍ Scribed by Bernasconi, Claude F.; Bhattacharya, Santanu

Book ID: 126061654
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 125 KB
Volume: 22
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om020748l

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Physical Organic Chemistry of Transition

Physical Organic Chemistry of Transition Metal Carbene Complexes. 29. † Kinetics of Reactions of [Ethoxy(phenyl)carbene]pentacarbonylchromium(0) and [Ethoxy(phenyl)(Cr(CO) 3 )carbene]pentacarbonylchromium(0) with Water, OH - , and Amines. Mechanistic Changes Induced by the Cr(CO) 3 Group

✍ Bernasconi, Claude F.; Bhattacharya, Santanu 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 133 KB

ChemInform Abstract: Physical Organic Ch

ChemInform Abstract: Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 11. Kinetics and Mechanism of the Hydrolysis of (2-Oxacyclopentylidene) pentacarbonylchromium(0) in Aqueous Acetonitrile.

✍ C. F. BERNASCONI; A. E. LEYES 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 11. Kinetics and Mechanism of the Hydrolysis of (2-Oxacyclopentylidene) pentacarbonylchromium(0) in Aqueous Acetonitrile.

Physical Organic Chemistry of Transition

Physical Organic Chemistry of Transition Metal Carbene Complexes. 24. Thermodynamic and Kinetic Acidities of Phenyl-Substituted (Benzylmethoxycarbene)pentacarbonylchromium(0) Complexes. Is There a Transition-State Imbalance? †

✍ Bernasconi, Claude F.; Sun, Weitao 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 95 KB

Physical Organic Chemistry of Transition

Physical Organic Chemistry of Transition Metal Carbene Complexes. 19. 1 Kinetics of Reversible Alkoxide Ion Addition to Substituted (Methoxyphenylcarbene)pentacarbonylchromium(0) and (Methoxyphenylcarbene)pentacarbonyltungsten(0) in Methanol and Aqueous Acetonitrile

✍ Bernasconi, Claude F.; García-Río, Luis 📂 Article 📅 2000 🏛 American Chemical Society 🌐 English ⚖ 221 KB

Kinetics of the Reactions of [ p -Nitrop

Kinetics of the Reactions of [ p -Nitrophenoxy(phenyl)carbene]pentacarbonylchromium(0) with Aryloxide Ions, Hydroxide Ion, and Water in Aqueous Acetonitrile. Concerted or Stepwise? †

✍ Bernasconi, Claude F.; Zoloff Michoff, Martin E.; de Rossi, Rita H.; Granados, A 📂 Article 📅 2007 🏛 American Chemical Society 🌐 English ⚖ 173 KB

Physical Organic Chemistry of Transition

Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 20: Kinetics and Mechanism of Reactions of (CO)5MC(OMe)C6H4X (M=Cr and W) with Primary Aliphatic Amines in Aqueous Acetonitrile. Substituent Effects

✍ Claude F. Bernasconi; Christina Whitesell; Rebecca A. Johnson 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 165 KB

AbstractÐA kinetic study of the reactions of (CO) 5 CrvC(OMe)C 6 H 4 X (X4-Cl, 4-F, H, 4-Me, 4-OMe and 4-NMe 2 ) and the respective tungsten carbene complexes with primary aliphatic amines (mainly n-butylamine) in 50% MeCN±50% water (v/v) at 258C is reported. The rate law is complex and shows OH 2 a