It has recently been demonstrated that hot-drawn samples of bisphenol A polycarbonate (PC) have a 50% higher volume relaxation rate than their isotropic counterpart even though the oriented samples have a lower initial free volume (i.e., higher density). 1 In an attempt to better understand this par
Physical aging of bisphenol A polycarbonate
✍ Scribed by S. Orreindy; A. Rincón G.
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 104 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
The physical aging of bisphenol A polycarbonate was studied using the differential scanning calorimetry technique. Cowie and Ferguson's model and Williams-Watts function were used to analyze the data. It is confirmed that the relation ⌬H ϱ (T a ) ϭ ⌬C p (T g Ϫ T a ), where ⌬H ϱ (T a ) is the value of the aging enthalpy for t ϭ ϱ, T a the aging temperature, and ⌬C p the difference in the specific heat above and below the glass transition temperature (T g ), can be used to study quantitatively the physical aging of bisphenol A polycarbonate.
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