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Phthalocyanine coatings on silica and zinc oxide: Synthesis and their activities in the oxidation of sulfide

✍ Scribed by Wöhrle, Dieter; Baziakina, Natascha; Suvorova, Olga; Makarov, Sergey; Kutureva, Valentina; Schupak, Elena; Schnurpfeil, Günter


Book ID
120917852
Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
585 KB
Volume
08
Category
Article
ISSN
1088-4246

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Polymeric cobalt(H)-phthalocyanine exhibited much higher specific catalytic activity in sulfide ion oxidation than the monomeric counterpart. Cobalt disproportionation, 2C02 + \*Co' + + Co3+, was observed with the polymeric phthalocyanine in alkali medium. A concerted process of the oxidation and re