𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Phototransformation of napropamide [ N , N -diethyl-2-(1-naphthyloxy)propionamide] in aqueous solution: influence on the toxicity of solutions

✍ Scribed by Aguer, J. P.; Boule, P.; Bonnemoy, F.; Chezal, J. M.

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
215 KB
Volume
54
Category
Article
ISSN
1526-498X

No coin nor oath required. For personal study only.

✦ Synopsis

The main photoproducts formed in an aqueous solution of napropamide irradiated in UV light are N,N-diethyl-2-(1-hydroxynaphthalen-2-yl)propionamide, N,N-diethyl-2-(4-hydroxynaphthalen-1-yl)propionamide and 1-naphthol. These account for c.60%, 15% and 10% of napropamide converted respectively. No inÑuence of the irradiation wavelength or of oxygen was observed. The same products were obtained by irradiation of methanolic solutions. The three identiÐed products result from the cleavage of naphthoxyÈ carbon bond. The Ðrst two products imply a photo-Fries rearrangement. The inÑuence of irradiation on the toxicity of the solutions was studied by the test. The signiÐcant increase observed may be attributed partly to Microtox} the formation of 1-naphthol. 1998

📜 SIMILAR VOLUMES

Effects of inorganic salts on the spectr
Effects of inorganic salts on the spectral behavior of poly(N-vinyl-2-pyrrolidone) in aqueous solutions
✍ Ali Güner 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB 👁 2 views

Electronic spectral behavior of poly(N-vinyl-2-pyrrolidone) (PVP) was determined in aqueous solutions including a variety of inorganic salts (phosphates, monoand dihydrogen phosphates, sulfates, chlorides, nitrates, bisulfites, and persulfates) for several concentrations. The n 3 \* excitations are

The Influence of Linker Geometry in Bis(
The Influence of Linker Geometry in Bis(3-hydroxy-N-methyl-pyridin-2-one) Ligands on Solution Phase Uranyl Affinity
✍ Dr. Géza Szigethy; Prof. Dr. Kenneth N. Raymond 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 404 KB

## Abstract Seven water‐soluble, tetradentate bis(3‐hydroxy‐__N__‐methyl‐pyridin‐2‐one) (bis‐Me‐3,2‐HOPO) ligands were synthesized that vary only in linker geometry and rigidity. Solution‐phase thermodynamic measurements were conducted between pH 1.6 and pH 9.0 to determine the effects of these var