Phototransformation of fibrate drugs in aqueous media
β Scribed by M. Cermola; M. DellaGreca; M.R. Iesce; L. Previtera; M. Rubino; F. Temussi; M. Brigante
- Book ID
- 106312896
- Publisher
- Springer-Verlag
- Year
- 2005
- Tongue
- English
- Weight
- 155 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1610-3653
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Porphyrin photoproducts with absorption maxima at 640 and 660 nm are formed in aqueous and micellar solutions during light exposure. Changes in the dimethoxyhaematoporphyrin (DMHp) Soret band on irradiation suggest that the photoproduct (640 nm) formation is conditioned by the "sandwich"-type self-a
The photolysis of dichlorophen (DCP) in acidic medium yields 4chloro-4-hydroxy-2,2'-methylenediphenol (I) in the absence of oxygen and a benzoquinone-like derivative (11) in oxygenated solution. At pH = 9, DCP is in monoanionic form, and three products, I, I1 and 4-chloro-2,2'-methylenediphenol (111