Phototoxicity and photonucleophilic aromatic substitution in chlorpromazine
β Scribed by Frederick W. Grant; James Greene
- Book ID
- 119001593
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 260 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0041-008X
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π SIMILAR VOLUMES
The kinetic data on the reactions of carbonylmetallates M'M(CO).L,, with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the reactivity of both carbanions, and non-transition metal centred anions.
Benzene and toluene. saturated with tritiated water, have been subjected to 6OCo y-radiation and UVlight. The yields of H-H substitution are higher for benzene than for toluene. Naphthalene decreases the substitution yield for benzene. The excited molecule mechanism of substitution is discussed. he