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Photoswitching of Cation Complexation with A Monoaza-crown Dithienylethene Photochrome

✍ Scribed by Malval, Jean-Pierre; Gosse, Isabelle; Morand, Jean-Pierre; Lapouyade, René


Book ID
120397860
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
39 KB
Volume
124
Category
Article
ISSN
0002-7863

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Structural and cation binding data for the title compound demonstrate that the large value of KS results from complete K+ cation encapsulation by one nitrogen and six oxygen atoms despite the presence of a twelve-membered macroring. In a previous study,' the myth of a hole-size relationship was dis