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Photostimulated Reactions of Phenylacetic Acid Dianions with Aryl Halides. Influence of the Metallic Cation on the Regiochemistry of Arylation

✍ Scribed by Nwokogu, Godson C.; Wong, Jim-Wah; Greenwood, Thomas D.; Wolfe, James F.


Book ID
126951246
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
51 KB
Volume
2
Category
Article
ISSN
1523-7060

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Y-Shaped ambident dianions 1-6 were reacted with cyclization reactions generally proceeded with good regioselectivity which is controlled by the heteroatoms of the dielectrophilic oxalic acid-bis(imidoyl)dichlorides 7 providing a convenient access to novel N-heterocycles 8-13 dianion reagents. conta