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Photostimulated reactions of haloarenes with 2-naphtylamide ions. A facile synthesis of 1-aryl-2-naphthylamines.

✍ Scribed by A.B. Pierini; M.T. Baumgartner; R.A. Rossi


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
235 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


The photostimulated reactions of aryl iodides with 2-naphthylamide ions in liquid the major substitution product. This reaction is ammonia gave 1-aryl-Z-naphthylamines as proposed to occur by the SRN 1 mechanism of nucleophilic substitution Organica, Facultad de Ciencias Quimicas, Suc.16, C.C.61, (5016) Cbrdoba, Argentina.


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SRN1 reaction of haloarenes with benzene
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## Abstract S~RN~1 reaction is of haloarenes with benzenethiolate, benzeneselenate, and benzenetellurolate ions can be carried out by use of samarium diiodide (SmI~2~) as a promoter in DMF‐THF to afford the corresponding ArZPh compounds in moderate to good yields. Β© 2001 John Wiley & Sons, Inc. Het