Photosensitized Asymmetric Isomerization and Cycloaddition of Cycloalkenes and Cycloalkadienes
β Scribed by Michael Oelgemoeller; Yoshihisa Inoue
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 49 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Quantum yield measurements for the S02(3B1) photosensitized isomerization of cis-1,2-diflu%roethylene have been made at 3712 A and 22Β°C. The ## [ S O ~] / [ C ~T -C ~F ~H Z ] ratio was varied from 47.4 to 455 and the quantum yield measurements over this variation of concentration ratios were consi
The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22Β°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma