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Photosensitized Asymmetric Isomerization and Cycloaddition of Cycloalkenes and Cycloalkadienes

✍ Scribed by Michael Oelgemoeller; Yoshihisa Inoue


Publisher
John Wiley and Sons
Year
2003
Weight
49 KB
Volume
34
Category
Article
ISSN
0931-7597

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The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22Β°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma